Apparatus for multilayer coextrusion of sheet or film

ABSTRACT

Multilayer coextrusion method and apparatus are shown which provide a relatively easily obtained symmetry control of the layer thickness which is particularly suitable when the desired laminate contains many layers.

United States Patent Schrenk 1 May 20, 1975 [54] APPARATUS FOR MULTILAYER 3,546,739 12/1970 Callahan et al. 425/ 131' I F HE R FILM 3,557,265 1/1971 Chisholm et al... 425/382 x COEXTRUS ON 0 S ET 0 3,565,985 2/1971 Schrenk et al 425/382 X [75] Inventor: Walter J. Schrenk, Bay City, MlCh. [73] Assignee: The Dow Chemical Company, FOREIGN PATENTS OR APPLICATIONS i d Mi h 354,837 8/1931 United Kingdom 425/131 374,148 6/1932 United Kingdom 425/131 [22] Filed: June 12, 1973 V e [211 App]. 369,372 Primary Examiner-R, Spencer Annear Related Application Data Attorney, Agent, or FirmRobert B. Ingraham [62] Division of Ser. No, 185,534, Oct. 1, 1971, Pat. No. 3

3,773,882 57 ABSTRACT [52] US. Cl 425/ 133.5; 264/ 171 Multilayer coextrusion method and apparatus are [51] Int. Cl B29f 3/12 shown which provide a relatively easily obtained sym- [58] Field Of Search 171 metry control of the layer thickness which is particularly suitable when the desired laminate contains many [56] References Cited layers.

UNITED STATES PATENTS 3 C 5 1 F 3,413,683 12/1968 Yelverton, Jr. 264/171 x D'awmg gums pmmwmzolrs sum 2 OF 2 Q g Y M w WWW W l mm I/GMN M w mm R 7% APPARATUS FOR MULTILAYER COEXTRUSION OF SHEET OR FILM This application is a divisional application of my copending application Ser. No. 185,534, filed Oct. 1,

1971, now U.S. Pat. No. 3,773,882.

Coextrusion or simultaneous extrusion of two or more synthetic resinous materials is well known in the art as is the desirability of preparing sheet or film containing many layers; e.g., 50, 100 or several hundred layers. The method and apparatus for such extrusion is disclosed in U.S. Pat. Nos. 3,565,985; 3,576,707 and 3,557,265, herewith incorporated by reference. Two general techniques are employed for the preparation of multilayer film having a relatively high number of layers. One involves what may be considered as the extrusion of a striped tube or a tube having materials encapsulated within the walls and subsequent rotation of the outer surfaces of the tube to distribute the material of the stripes in a spiral configuration which, on examination of the tube, gives the appearance of having many parallel layers. An alternate method for the production of a many layered sheet wherein all of the layers are generally parallel basically may be considered as the simultaneous extrusion of a striped sheet, compressing the sheet in the direction of its width, expanding the sheet in the direction of its thickness to provide a sheet having a number of parallel layers which may equal or be more or less a multiple of the number of stripes originally present in a striped sheet. In effect, the edges of the originally extruded striped sheet have become the major surfaces of the layered sheet and the major surfaces of the striped sheet have become the edges. For many applications it is desirable that very precise control be achieved in the thickness of the layers of sheet or film which is ultimately extruded. In employing apparatus, for example as is illustrated in U.S. Pat. No. 3,557,265 where in essence the striped sheet is prepared by combining two streams in a feed block or stream divider in such a way that the streams are interdigitated, if all of the feed slots are of equal size the resultant film obtained from such an apparatus shows a small but finite gradation in thickness of the layers. The layers adjacent the surface of the film exhibit minimal thickness while the layers in the central portion exhibit maximum thickness. Correction of such variations can be accomplished by conventional die working means wherein the feed ports, slots or channels which provide polymer for the outer layers can be enlarged or reduced in an appropriate manner until the desired thickness distribution or uniformity is obtained. Such a procedure is very expensive, time consuming and dependent on a substantial amount of trial and error. One difficulty which exists in the preparation of multiple layer, simultaneously extruded films particularly employing apparatus of the nature set forth in U.S. Pat. No. 3,557,265, which for convenience may be referred to as a linear feed block system, is the physical length of the feed block or feed port section. If large numbers of layers are required in an extrusion apparatus, certain practical mechanical limitations, depending on the rheology of the system, dictate that the individual feed passageways be of a minimal width to avoid plugging in the event minor foreign contaminants are present in the heat plastified resinous material forwarded to the feed passageways. Dividers between the feed passageways generally must be maintained above a minimal thickness, depending upon the particular material of construction in order to resist deformation due to any pressure unbalance between adjacent passageways and to reasonably resist damage during service, manufacture, assembly and disassembly of the apparatus when cleaning or adjustment is necessary.

It would be desirable if there were available an improved method and apparatus for the preparation of multilayer, simultaneously extruded bodies which would provide substantially greater uniformity of layer thickness in the final product without the necessity of individual adjustment of feed passageways.

These benefits and other advantages in accordance with the present invention are achieved in an apparatus for the preparation of multilayer film and sheet, the apparatus comprising a body, the body defining at least a first polymer entry passage, a first plenum in communication with the first polymer passage, a stream dividing means to divide material flowing from the first passage into a plurality of first substreams, a second polymer receiving means in operative communication with a second plenum, the second plenum discharging to the dividing means which divides the second stream into a plurality of second substreams and interdigitates the second substreams with the first substreams, the dividing means being in operative communication with a third or composite stream receiving plenum, the composite stream comprising the combined first and second substreams, a third plenum discharge passage in operative communication with the third plenum and adapted to receive the composite stream from the third plenum, the discharge means being in combination with external stream shaping means, the discharge passage having a first or receiving end and a second or discharge end, the improvement which comprises disposing the discharge portion of the stream dividing means in a generally arcuate manner generally equidistant from the inlet end of the third plenum discharge passage.

Also contemplated within the scope of the present invention is a method for the preparation of a composite stream of interdigitated diverse synthetic resinous material, the steps of the method comprising providing at least a first stream of a heat plastified synthetic resinous material and a second stream of heat plastified thermoplastic material, dividing each of the streams into a plurality of first substreams, and a plurality of second substreams respectively, combining the substreams to form a composite stream having the first substreams and the second substream interdigitated, deforming the composite stream by causing the substreams to flow in a generally radially inward manner to a discharge location, the discharge location being generally equidistant from locations of combination of adjacent first and second substreams.

Further features and advantages of the present invention will become more apparent from the following specification taken in connection with the drawing wherein:

FIG. 1 schematically represents preparation of multilayer film employing apparatus in accordance with the present invention.

FIG. 2 is a schematic sectional representation of stream combining apparatus of FIG. 1.

FIG. 3 is a schematic partially cutaway view of the apparatus of FIG. 2.

FIGS. 4 and 5 schematically depict views of the stream divider of the apparatus of FIGS. 2 and 3.

' In FIG. 1 there is schematically depicted apparatus and method of the present invention generally designated by the reference numeral 10. The apparatus comprises in cooperative combination first, second and third sources of heat plastified thermoplastic resinous material designated as 11, 12 and 13, respectively, which beneficially are extruders. A stream combining means 15 is in operative communication with the extruders 11, 12 and 13 by suitable conduits 16, 17 and 18, respectively. The apparatus or stream combining means 15 has a discharge means 19 which is in operative communication with a stream shaping means or film or sheeting die 21. The die 21 has a generally slotlike extrusion orifice 22. A laminate or multilayer stream 23 is passed from the orifice 22 and wound onto the roll 24. The die 21 may have a convenient shape or configuration generally employed in the art of multiple extrusion. Such dies are well known and some are schematically depicted in US. Pat. Nos. 3,397,428; 3,399,105; 3,423,498; 3,479,425; 3,487,505; 3,511,903; 3,549,405; 3,555,128; 3,557,265 and 3,565,985, herewith incorporated by reference.

In operation of the apparatus of FIG. 1, the sources l1, l2 and 13 supply heat plastified synthetic resinous material through the conduits 16, 17 and 18, respectively, to the combining apparatus 15 wherein the streams are divided, interdigitated and passed to the discharge 19 to form a composite layered stream having layers parallel to the die orifice 22. Within the die 21 flow rate is maintained to permit streamlined flow and the stream is deformed into the film 23 which is cooled by means not shown and wound onto the roll 24.

FIG. 2 is a schematic representation of a section through a stream combining means 15a. The operation of the stream combining means 15a is generally similar to that of the stream combining means 15 of FIG. 1. The stream combining means 15a comprises a body 25. The body 25 comprises a first outer portion 25a and a second outer portion 25b. The first and second body portions 25a and 25b are held in fixed relationship by a plurality of fasteners 26 such as cap screws. The body or housing 25 defines a first inlet port or passage 28 generally axially extending and a second polymer inlet 29 also generally axially extending. Within the body 29 is a generally cylindrical cavity 31 which is in full communication with the passages 28 and 29. A body portion 25b defines two third polymer inlet passages 32 generally displaced but parallel to the axially disposed passages 28 and 29. Within the cavity 31 is a second or inner housing 33 composed of a first housing portion 33a and a second housing portion 33b. The first housing portion 33a and the housing portion 25b define a first polymer receiving cavity 35 which is of generally discoidal configuration. The inner housing portion 33b and the outer housing portion 25a define a second plenum 37 also of generally discoidal configuration. A plurality of stiffening ribs 38 integral with the portion 25b radially extend between the inner housing portion 33a and the housing portion 25b within the plenum 35. Similar ribs 39 integral with the housing portion 25a are disposed in the plenum 37. Generally peripherally disposed within the housing 33 is a third plenum 41 having the configuration of a major radial segment of a toroid. The plenum 41 is in communication with the third passages 32. A stream dividing means 42 is disposed within the inner housing 33 and has defined 33a and 33b. The passage 46 has an inlet end 47 and a discharge end 48. The inlet end 47 is generally equidistant from the discharge locations of the distributor In FIG. 3 there is depicted a schematic partially cutaway plan view of the distributor 15a with a portion of the body portion 25b removed and a portion of the inner body portion 33b removed. The distributor 42 has disposed therein a plurality of slots or feed passages 51 which communicate with the plenum 41. The slots 51 have an inlet opening 52 adjacent the plenum 41 and outlet openings 53 discharging into the third plenum 44. A series of passages 55 disposed intermediate some of the passages 52 communicate with the plenum 37, not shown. The passages 55 as depicted in FIG. 2 are bifurcated and terminate at their discharge end generally adjacent the discharge ends 53 of the passages 51. Similar bifurcated passages 56 are provided in alternating arrangement and communicate with the plenum 35 and terminate adjacent the discharge ends 53 of the passages 51. The plenum 44 has a generally discoidal configuration with a sector removed and terminates at surfaces 56 and 57, and the surfaces 56 and 57 are generally radially and axially extending. At the terminal portions of the stream dividing means 42 are provided major polymer passages 55a which are in communication with the plenum 35 and communicate with a plurality of minor passages similar in dimension to the passages 51 and terminate at a location generally equidistant from the center of the distributor 42.

FIG. 4 is a sectional schematic representation of the construction of the stream divider 42. The divider 42 consists of a first body portion 42a having a plurality of peripheral, generally axially extending passages 61, the stream divider having the general configuration of an arc of a circle. A plurality of radially extending fin-like elements 62 define therebetween radially extending passages, some of which communicate with the passages 61. A second body portion 42b of generally annular configuration is disposed generally in'contact with the fin-like elements 62. The body portion 42b defines a plurality of peripherally disposed generally axially directed passages 64 adapted to communicate with the passages defined between the fin-like elements 62. A peripheral ring 65 is disposed about the body portion 42a and has defined therein a plurality of slots 66 adapted to communicate with spaces between the finlike elements 62.

FIG. 5 schematically depicts a view of the distributor 42 looking radially inward showing the locations of the passages 64, 61 and 66, each of the passages 61, 64 and 66 being in full communication with a passage 62a defined between adjacent fins 62. For purposes of clarity of illustration, alternate fins 62 which bifurcate the passages have been omitted.

In operation of the apparatus as depicted in FIGS. 25, the first polymer is introduced into the polymer 1 passage 28 which in turn flows into the plenum 37, is

discharged into the passage 56 and between the fins 62 and is discharged into the plenum 44. A substantially greater portion is discharged to the passage 55a adjacent the surfaces 56 and 57. The second polymer is introduced into the passage 29 which in turn flows into the plenum 37 and is taken from the plenum 37 by the passage 56 and discharged by the communicating passages 66 into the plenum 44 between materials coming from the plenum 35. The third material is introduced into the plenum 41 and flows through the passages 66 into the mating passages 62a, thus providing a radially inwardly flowing stream of a desired layered configuration. As the resultantstream flows inwardly and approximately a distance equidistant from the entrance 47 of the discharge passage 46, the layer thickness of the various layers in the composite stream is proportional to the number of passages 62a, assuming equal volumetric flow through the passage.-

The apparatus in accordance with the present invention is employed with particular advantage in the extrusjon of synthetic resinous composite film and sheet. Employing an apparatus such as hereinbefore set forth, a substantial improvement in uniformity of film layer is obtained.

As is apparent from the foregoing specification, the present invention is susceptible of being embodied with various alterations and modifications which may differ particularly from those that have been described in the preceding specification and description. For this reason, it is to be fully understood that all of the foregoing is intended to be merely illustrative and is not to be construed or interpreted as being restrictive or otherwise limiting of the present invention.

What is claimed is:

1. An apparatus for the preparation of a multilayer film or sheet, the apparatus comprising a body, the body defining at least a first polymer entrance passage,

a first plenum in communication with the first polymer passage,

a stream dividing means to divide material flowing from the first passage into a plurality of first substreams,

second polymer receiving means in operative communication with a second plenum, the second plenum discharging to the dividing means which divides the second stream into a plurality of second substrearns and interdigitates the plurality of second substrearns with the first substrearns, the dividing means being in operative communication with a third or composite stream receiving plenum, the composite stream comprising the combined first and second substrearns,

a third plenum discharge passage in operative communication with the third plenum and adapted to receive the composite stream from the third plenum, the discharge means being in combination with a die having a generally slot-like extrusion orifice, the

discharge passage having a first or receiving end and a second or discharge end, the improvement which comprises disposing the discharge portion of the stream dividing means in an arcuate manner to form an arc of a circle wherein the discharge portion is generally equidistant from the discharge end of the third plenum discharge passage.

2. The apparatus of claim 1 including a third polymer receiving means in communication with a third polymer receiving plenum, the third polymer receiving plenum discharging to the stream dividing means to provide a plurality of third substrearns which are interdigitated with the first and second substreams.

3. The apparatus of claim 1 in operative combination with means to supply first and second streams of heat plastifiedsynthetic resinous material. 

1. An apparatus for the preparation of a multilayer film or sheet, the apparatus comprising a body, the body defining at least a first polymer entrance passage, a first plenum in communication with the first polymer passage, a stream dividing means to divide material flowing from the first passage into a plurality of first substreams, second polymer receiving means in operative communication with a second plenum, the second plenum discharging to the dividing means which divides the second stream into a plurality of second substreams and interdigitates the plurality of second substreams with the first substreams, the dividing means being in operative communication with a third or composite stream receiving plenum, the composite stream comprising the combined first and second substreams, a third plenum discharge passage in operative communication with the third plenum and adapted to receive the composite stream from the third plenum, the discharge means being in combination with a die having a generally slot-like extrusion orifice, the discharge passage having a first or receiving end and a second or discharge end, the improvement which comprises disposing the discharge portion of the stream dividing means in an arcuate manner to form an arc of a circle wherein the discharge portion is generally equidistant from the discharge end of the third plenum discharge passage.
 2. The apparatus of claim 1 including a third polymer receiving means in communication with a third polymer receiving plenum, the third polymer receiving plenum discharging to the stream dividing means to provide a plurality of third substreams which are interdigitated with the first and second substreams.
 3. The apparatus of claim 1 in operative combination with means to supply first and second streams of heat plastified synthetic resinous material. 